Aroma is perceived by two different mechanisms. It can either be sensed nasally via smelling the coffee through the nose or retronasally. Retronasal perception occurs when the coffee is either present in the mouth or has been swallowed and aromatic volatile compounds drift upward into the nasal passage.
The number of aromatic compounds found in coffee increases every year.
Today, the number is well over 800 and as our analytical methods become more precise more will be uncovered. Yet, the perception of aroma is dependent upon both the concentration of the compound and its odor threshold. With that said, understanding coffee aroma is not as difficult as understanding how over 800 compounds interact with the olfactory epithelium. It is probable that a relatively small group of compounds that share both a high concentration and a low odor threshold make up the fragrance we know as coffee aroma.
Listed the following the development of volatile compounds in coffee :
1) Maillard or non-enzymatic browning reaction between nitrogen containing substances, amino acids, proteins, as well as trigonelline, serotonine, and carbohydrates, hydroxy-acids and phenols on the other.
2) Strecker degradation.
3) Degradation of individual amino acids, particularly, sulfur amino acids, hydroxy amino acids, and proline.
4) Degradation of trigonelline.
5) Degradation of sugar.
6) Degradation of phenolic acids, particularly the quinic acid moiety.
7) Minor lipid degradation.
8) Interaction between intermediate decomposition products.
Source: Coffeeresearch.org
Coffee Flavor